How to produce βtype semihydrated gypsum βCaSO2·12H2O
Microstructure and mechanical properties of βhemihydrate
2011年7月1日 This article addresses the microstructure and related mechanical properties of gypsum produced from βhemihydrate using information of its hydration process, from fresh Hemihydrate occurs in two formations of α and βtype Among them βhemihydrate is mainly used to produce gypsum plasterboard since the hydration product of the αhemihydrate is too Gypsum hydration: a theoretical and experimental study2019年4月26日 In the hightemperature and low water vapor pressure region, gypsum dehydrates to form γCaSO 4 in a singlestep process (CaSO 4 2H 2 O → γCaSO 4); with Dehydration Pathways of Gypsum and the Rehydration 2007年3月1日 The properties of the two hemihydrates (α and β), their hydration characteristics, the mechanism of their hydration and the crystal growth of gypsum are discussed Additives Calcium sulphate hemihydrate hydration leading to gypsum
Gypsum hydration: A theoretical and experimental study
2009年1月1日 Quasistoichiometric w values permit the production of gypsumbonded composite materials of low porosity which exhibit a relatively high tendency to swelling during Two–step process in the dehydration of gypsum Supplementary Figure S1 (Fig S1–S4 are available online from https://doi/102465/jmps) shows the TG and DTA curves of Structural evolution of gypsum (CaSO42H2O) during thermal This article addresses the microstructure and mechanical properties of a βhemihydrate produced gypsum from a combined study of hydration and dehydration A thin layer of adsorbed water Gypsum: an investigation of microstructure and mechanical 2009年9月23日 The microstructure development of gypsum during hydration is investigated The influence of water is studied from its effect on fresh behavior and void fraction of the gypsum Gypsum hydration: a theoretical and experimental study
Calcination Processes Gypsum: Connecting Science and
The preparation of natural and synthetic gypsum prior to calcination, such as drying and grinding The various calcination methods for β hemihydrate and α hemihydrate are reviewed, such as Hemihydrate occurs in two formations of α and βtype Among them βhemihydrate is mainly used to produce gypsum plasterboard since the hydration product of the αhemihydrate is too Gypsum hydration: a theoretical and experimental studyIf the dehydrating process of dihydrate gypsum is in a dry environment lacking water steam, then β − CaSO 4 1 2 H 2 O is produced, called common building gypsum, and α − CaSO 4 1 2 H 2, high strength building gypsum, ß type hemihydrate gypsum is irregular scaly secondary particles, which are made up of very small single crystals, a type hemihydrate gypsum is made up of Gypsum Product an overview ScienceDirect Topics2020年11月23日 Using solar energy to dehydrate gypsum to produce βhemihydrate is one way to improve the carbon footprint 13,14 Alternatively, αhemihydrate is produced from gypsum using an autoclave process 15Preparation of αcalcium sulfate hemihydrate from industrial by
Calcium Sulfate Hemihydrate an overview ScienceDirect Topics
Naturally occurring crystals are calcium sulfate dihydrate, CaSO 4 2H 2 O, known as gypsum, and anhydrous calcium sulfate, IICaSO 4 When gypsum is heated, dehydration occurs to form hemihydrates, CaSO 4 1/2H 2 O, followed by anhydrite, IIICaSO 4 The hemihydrates and the anhydrite have two modifications, α and β, respectivelyA special type of plaster, called alpha hemihydrate, can be produced by reacting the raw material under high pressure steam in strictly controlled conditions This plaster sets harder and is used in dental work and as a modelling plaster, but is impossible to produce without expensive production equipment Properties of gypsum plasterGypsum processing and use Humanitarian Library2023年5月15日 Figure 1: a: Gypsum crystals produced from sodium sulphate and calcium chloride; b: Natural gypsum cut along black lines; c: Gypsum crystals from a, with directions from Figure 2 marked with arrows, on side from Figure 3 marked with yellow, on cleavage plane with red; d: Crystal from a) along caxis marked in blackUnderstanding gypsum in 3 diagramsSemihydrate gypsum (CaSO 4⋅05H 2O) is usually obtained from dihydrate gypsum (CaSO 4⋅2H 2O) When dihydrate gypsum is treated in the saturated vapour at 120 °C and pressure 013 MPa, it results in a loss of hydration water (H 2O) [18] The dehydration of dihydrate gypsum to αsemihydrate gypsum occurs according to theInfluence of Ce on the Formation of SemiHydrate Gypsum KTU
Plaster of Paris Structure, Properties, Preparation, Uses, and FAQs
2024年4月17日 Gypsum Plaster of Paris Gypsum is a hydrated calcium sulphate mineral with the molecular formula CaSO 4 2H 2 O : Plaster of Paris is a commonly used mineral obtained by Gypsum and has a chemical formula CaSO 4 1/2H 2 O : It is a Dihydrate compound2022年4月1日 besides, the transformation of the Ca–OH 2O(Ca,S) interchain linkage (Fig 2) into Ca–O(Ca,S) leads to a change in the coordination of calcium, from CaO 6 (H 2 O) 2 in gypsum to CaO 8 in anhydrite A survey of the “recent” crystallographic data available for the two phases (see Supplementary Information) reveals a stretching of the chain periodicity, from From atom level to macroscopic scale: Structural mechanism of gypsum 2011年7月1日 This article addresses the microstructure and related mechanical properties of gypsum produced from βhemihydrate using information of its hydration process, from fresh paste to hardened gypsum Microstructure and mechanical properties of βhemihydrate 2007年3月1日 Calcium sulphate hemihydrate commonly known as plaster of Paris is extensively used in buildings, ceramics and medical industries Hydration of hemihydrate is a highly exothermic reaction and occurs as: CaSO 4 05 H 2 O + 15 H 2 O ⇒ CaSO 4 2 H 2 O + Q where Q the amount of heat evolved depends on number of factors During hydration, gypsum Calcium sulphate hemihydrate hydration leading to gypsum
Autoclave‐Free Formation of α‐Hemihydrate Gypsum
2005年3月8日 The βtype hemihydrate gypsum is formed through the dehydration of dihydrate gypsum in a dry environment, but its products feature low mechanical strength, vulnerability to temperature, and poor 2022年5月9日 Depending on different preparation conditions [8,9], it can obtain two forms of hemihydrate gypsum, α and β hemihydrate gypsum, which are denoted as αHH and βHH, respectively Many scholars believe that the cell parameters of αHH and βHH are identical since no obvious differences between the two forms have been concluded by modern testing and Experimental Study and Mechanism Analysis of Preparation of α 2023年7月1日 Table 1 displays the PG's chemical compositions employed by various researchers There is some variation in the chemical composition of PG from study to study PG primarily contains CaO and SO 3, about 65% of the overall massAdditionally, PG includes organic materials, sulphides, Al, Mg and Fe 2 O 3 [30]When PG is recycled, contaminants in Review Article Recent research in utilization of phosphogypsum as 2015年9月30日 The adequate water content allows the hydration of the β semihydrated gypsum, which produces the hardening and shaping of the bihydrated gypsum (CaSO 4 2H 2 O) In the case of an excessive amount of water, due to water loss during the heating process, bricks with lower density and poor mechanical properties are producedThe influence of hydration and swelling properties of gypsum on
Gypsum: a review of its role in the deterioration of Springer
2006年12月2日 The deterioration of buildings and monuments by gypsum is the result of crystallization cycles of this salt Although gypsum can dehydrate to a hemihydrate, the mineral bassanite, and to an anhydrate, the mineral anhydrite, this reaction occurs in nature on a geological time scale and therefore it is unlikely to occur when gypsum is found on and in If the dehydrating process of dihydrate gypsum is in a dry environment lacking water steam, then β − CaSO 4 1 2 H 2 O is produced, called common building gypsum, and α − CaSO 4 1 2 H 2, high strength building gypsum, ß type hemihydrate gypsum is irregular scaly secondary particles, which are made up of very small single crystals, a type hemihydrate gypsum is made up of Building Gypsum an overview ScienceDirect TopicsThe invention discloses a method for producing semihydrated gypsum by using a salt solution, comprising the following steps: adding dihydrate gypsum in the salt solution, reacting for 152 h at the constant temperature of 95 DEG C under normal pressure, then filtering and drying to obtain the semihydrated gypsum Compared with the prior art, the salt solution has high utilization Method for producing semihydrated gypsum by using salt Figures 269 and 270 show the appearance of hydrated gypsum plaster from the same natural British source, chiefly comprising a mass of small, interlocking crystals of gypsum with firstorder grey interference colours Larger gypsum crystals are seen filling voids Ironrich clay impurities are still present and clearly identifiable by their red colourGypsum Plaster an overview ScienceDirect Topics
Physical and mechanical properties of semihydrated gypsum
Download scientific diagram Physical and mechanical properties of semihydrated gypsum from publication: Development of EnvironmentFriendly Plastering Gypsum A new type of plastering gypsum When producing gypsum products, αtype semihydrated gypsum requires less water than βtype, and the products have higher compactness and strength 2 With the continuous progress of hydration, βtype hemihydrate gypsum produces more ALPHA GYPSUM POWDER VS BETA GYPSUM POWDER VISIGHTGypsum/Anhydrite are produced from opencast mines, or underground mines using pillar and stall mining methods, that give extraction rates of up to 75% Gypsum is normally only screened to remove ‘fines’ (mainly mudstones), then crushed and finely ground Gypsum/Anhydrite for cement manufacture is supplied in crushed form for further fineFactsheet on: What is Gypsum?αpinene; methoxylation; potassium alum; catalyst 1 Introduction αPinene is the main constituent of turpentine, the essential oil obtained from pine gum, in Pine trees, making cuts in the trunk openings of the wood (similar to the extraction of latex for rubber in Hevea brasiliensis) so the resin present in the resinous channels exudes under pressure [1, 2]Potassium Alum [KAl(SO4)2∙12H2O] solid catalyst for effective and
Influence of the Calcination Temperature of Synthetic
2020年10月28日 The setting time depends on the type o f binder, dihydrate gypsum into semiaqueous gypsum and methylcellulose, lime flour, perlite, hydrated lime, and water Energies 2020, 13, 5759 6 2022年10月1日 Request PDF Preparation of Superfine and SemiHydrated Flue Gas Desulfurization Gypsum Powder by a Superheated Steam Powdered Jet Mill and Its Application to Produce Cement Pastes The low Preparation of Superfine and SemiHydrated Flue Gasβtype hemihydrate gypsum is a flaky and cracked crystal with excellent crystals Alpha gypsums specific surface area is much larger than that of αtype hemihydrate gypsum When producing gypsum products, αtype semihydrated gypsum requires less water than βtype, and the products have higher compactness and strength 2ALPHA GYPSUM Ataman Kimya AŞ2023年9月23日 The βhemihydrate gypsum, the other type of hemihydrate gypsum, is obtained through the hightemperature calcination o f dihydrate gypsum, resulting in the los s of 15 crystal water molecules(PDF) Application and Development Prospects of Phosphogypsum
Calcium sulfate Wikipedia
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydratesIn the form of γanhydrite (the anhydrous form), it is used as a desiccantOne particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsumIt has many uses in industry All forms are white solids that are poorly soluble in atomic coordinates of gypsum were adopted from Comodi et al (2008) Because β–hemihydrate and soluble anhydrite were indistinguishable from the powder XRD pattern, an attempt to calculate the two–phase mixture model of β–hemihydrate and soluble anhydrite did not yield reliable quantitative values during refinementStructural evolution of gypsum (CaSO42H2O) during thermal 2021年8月16日 Gypsum plaster, also known as plaster of Paris, is one of the earliest materials used for construction [1], [2], [3], whose use can be traced back to several thousands of years agoNow, it is still primarily used for indoor applications owing to a whole bunch of advantageous attributes, such as easy fabrication feature, thermal insulation, environmental friendliness, fire Hydration characteristics and mechanism analysis of βcalcium In previous studies, the existence of βCaSO4 05H2O was not observed as an intermediate phase during thermal decomposition of gypsum to anhydrite; ie, one phase transition was reported of gypsum to CaSO4 05H2O at 70 °C and one for CaSO4 05H2O to anhydrite at 280 °C52 Similarly, dry dehydration of CaSO4 2H2O studied by powder neutron diffraction (PDF) Formation and Transformation of Five Different
Improving properties of highvolume fly ash cement paste
2020年11月20日 The use of βhemihydrate as building material is more common than the use of αhemihydrate, since the hydration product of αhemihydrate is too brittle [8]As reported in some published literature [9], βhemihydrate can also be used to produce low heat sulfateactivated cementitious material, such as slagThe addition of βhemihydrate not only increased the 2022年1月1日 The result indicates that calcination at low temperature for the manufacture of βhemihydrate gypsum resulted in no change in harmful impurities, which adversely affects the properties of gypsum plaster; however, the calcination at high temperatures for the production of anhydrite could remove the harmful impurities and converted them into stable compounds, Recycling of phosphogypsum to prepare gypsum plaster: Effect is usually used to produce gypsum plasterboard Hemihydrate occurs in two forms, ie the a and btype, whereas bhemihydrate is mainly applied since the hydration product of the ahemihydrate is too brittle to be used as building material The properties of gypsum are influenced by the hydration process and the properties of the hemihydrateMicrostructure and mechanical properties of βhemihydrate 2018年5月1日 Request PDF Synthesis of αhemihydrate gypsum from cleaner phosphogypsum Phosphogypsum (PG), as a waste byproduct with high content and complicated impurities, is difficult to be utilised Synthesis of αhemihydrate gypsum from cleaner phosphogypsum
Infrared studies of water in crystalline hydrates: gypsum,
2011年2月3日 Infrared spectra of partially deuterated hydrates yield the fundamental frequencies of isotopically dilute H2O, D2O, and HDO molecules Isotopic dilution eliminates vibrational coupling and allows 2000年12月1日 While additives have been widely used to inhibit the precipitation of calcium sulfate, and also to some extent to modify the morphology of gypsum, it is remarkable that no report has been made of Hydration of calcium sulfate hemihydrate (CaSO 4 1 2 H 2O) into 2011年6月1日 The transformation of gypsum into anhydrite at low temperatures under atmospheric pressure as well as at elevated temperatures (150 °C and 200 °C) inside an autoclave was investigated by monitoring changes in both the liquid and solid phases The effect of temperature, sulfuric acid addition, anhydrite seeding and addition of sulfate and chloride Mechanism and kinetics of gypsum–anhydrite ScienceDirect2008年6月24日 ChemInform Abstract: Formation and Transformation of Five Different Phases in the CaSO 4 H 2 O System: Crystal Structure of the Subhydrate βCaSO 4 ×05H 2 O and Soluble Anhydrite CaSO 4ChemInform Abstract: Formation and Transformation of Five
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The total shrinkage of β gypsum at 740 ° C is higher than the shrinkage of αgypsum, and the size of β gypsum sample still continues to change during the process of constant temperature, indicating that the strength of β gypsum sample is reducing significantly When it heats to above 700 ° C, the βgypsum does not have sufficient strength to2015年7月16日 Single crystals were grown at room temperature from the precursors CaCO3 and NH2SO3H by a gel method using agaragar gel as the medium of growth(PDF) Synthesis, Crystal Structure, and Thermal Properties of